全文获取类型
收费全文 | 20488篇 |
免费 | 3189篇 |
国内免费 | 1819篇 |
专业分类
化学 | 13593篇 |
晶体学 | 100篇 |
力学 | 775篇 |
综合类 | 206篇 |
数学 | 6384篇 |
物理学 | 4438篇 |
出版年
2024年 | 15篇 |
2023年 | 243篇 |
2022年 | 363篇 |
2021年 | 733篇 |
2020年 | 998篇 |
2019年 | 829篇 |
2018年 | 749篇 |
2017年 | 886篇 |
2016年 | 1199篇 |
2015年 | 1110篇 |
2014年 | 1426篇 |
2013年 | 1916篇 |
2012年 | 1524篇 |
2011年 | 1485篇 |
2010年 | 1207篇 |
2009年 | 1293篇 |
2008年 | 1263篇 |
2007年 | 1193篇 |
2006年 | 1053篇 |
2005年 | 909篇 |
2004年 | 703篇 |
2003年 | 621篇 |
2002年 | 560篇 |
2001年 | 497篇 |
2000年 | 383篇 |
1999年 | 358篇 |
1998年 | 276篇 |
1997年 | 241篇 |
1996年 | 217篇 |
1995年 | 196篇 |
1994年 | 148篇 |
1993年 | 117篇 |
1992年 | 113篇 |
1991年 | 102篇 |
1990年 | 77篇 |
1989年 | 59篇 |
1988年 | 51篇 |
1987年 | 48篇 |
1986年 | 45篇 |
1985年 | 52篇 |
1984年 | 54篇 |
1983年 | 21篇 |
1982年 | 34篇 |
1981年 | 18篇 |
1980年 | 20篇 |
1979年 | 26篇 |
1978年 | 11篇 |
1977年 | 15篇 |
1976年 | 11篇 |
1974年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
22.
Mechanical property and deformation mechanism of gold nanowire with non-uniform distribution of twinned boundaries:A molecular dynamics simulation study 下载免费PDF全文
《中国物理 B》2021,30(5):56101-056101
The mechanical property and deformation mechanism of twinned gold nanowire with non-uniform distribution of twinned boundaries(TBs) are studied by the molecular dynamics(MD) method. It is found that the twin boundary spacing(TBS) has a great effect on the strength and plasticity of the nanowires with uniform distribution of TBs. And the strength enhances with the decrease of TBS, while its plasticity declines. For the nanowires with non-uniform distribution of TBs, the differences in distribution among different TBSs have little effect on the Young's modulus or strength, and the compromise in strength appears. But the differences have a remarkable effect on the plasticity of twinned gold nanowire. The twinned gold nanowire with higher local symmetry ratio has better plasticity. The initial dislocations always form in the largest TBS and the fracture always appears at or near the twin boundaries adjacent to the smallest TBS. Some simulation results are consistent with the experimental results. 相似文献
23.
24.
Dengfeng LI 《Frontiers of Mathematics in China》2022,17(4):501
This paper introduces an open conjecture in time-frequency analysis on the linear independence of a finite set of time-frequency shifts of a given L2 function. Firstly, background and motivation for the conjecture are provided. Secondly, the main progress of this linear independence in the past twenty five years is reviewed. Finally, the partial results of the high dimensional case and other cases for the conjecture are briefly presented. 相似文献
25.
26.
Dr. Lukas Kaltschnee Dr. Anil P. Jagtap Dr. Jeffrey McCormick Dr. Shawn Wagner Prof. Dr. Louis-S. Bouchard Prof. Dr. Marcel Utz Prof. Dr. Christian Griesinger Dr. Stefan Glöggler 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(47):11031-11035
NMR offers many possibilities in chemical analysis, structural investigations, and medical diagnostics. Although it is broadly used, one of NMR spectroscopies main drawbacks is low sensitivity. Hyperpolarization techniques enhance NMR signals by more than four orders of magnitude allowing the design of new contrast agents. Parahydrogen induced polarization that utilizes the para-hydrogen's singlet state to create enhanced signals is of particular interest since it allows to produce molecular imaging agents within seconds. Herein, we present a strategy for signal enhancement of the carbonyl 13C in amino acids by using parahydrogen, as demonstrated for glycine and alanine. Importantly, the hyperpolarization step is carried out in water and chemically unmodified canonical amino acids are obtained. Our approach thus offers a high degree of biocompatibility, which is crucial for further application. The rapid sample hyperpolarization (within seconds) may enable the continuous production of biologically useful probes, such as metabolic contrast agents or probes for structural biology. 相似文献
27.
Bahareh Heidari Majid M. Heravi Mohammad Reza Nabid Roya Sedghi Seyyed Emad Hooshmand 《应用有机金属化学》2019,33(1)
A novel nanocatalyst was designed and prepared. Initially, the surface of magnetic graphene oxide (M‐GO) was modified using thionyl chloride, tris(hydroxymethyl)aminomethane and acryloyl chloride as linkers which provide reactive C═C bonds for the polymerization of vinylic monomers. Separately, β‐cyclodextrin (β‐CD) was treated with acryloyl chloride to provide a modified β‐CD. Then, in the presence methylenebisacrylamide as a cross‐linker, monomers of modified β‐CD and acrylamide were polymerized on the surface of the pre‐prepared M‐GO. Finally, palladium acetate and sodium borohydride were added to this composite to afford supported palladium nanoparticles. This fabricated nanocomposite was fully characterized using various techniques. The efficiency of this easily separable and reusable heterogeneous catalyst was successfully examined in Suzuki–Miyaura cross‐coupling reactions of aryl halides and boronic acid as well as in modified Suzuki–Miyaura cross‐coupling reactions of N‐acylsuccinimides and boronic acid in green media. The results showed that the nanocatalyst was efficient in coupling reactions for direct formation of the corresponding biphenyl as well as benzophenone derivatives in green media based on bio‐based solvents. In addition, the nanocatalyst was easily separable, using an external magnet, and could be reused several times without significant loss of activity under the optimum reaction conditions. 相似文献
28.
Dr. Oliver Hegen Jens Braese Prof. Dr. Alexey Y. Timoshkin Prof. Dr. Manfred Scheer 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(2):485-489
A new class of neutral bidentate ligands with pnictogenyl-functional sites has been obtained. The reaction of tmeda⋅(BH2I)2 ( 1 , tmeda=tetramethylethylendiamine) with different phosphanides yields the corresponding bidentate phosphanylboranes tmeda⋅(BH2PH2)2 ( 2 a ), tmeda⋅(BH2PPh2)2 ( 2 b ), and tmeda⋅(BH2tBuPH)2 ( 2 c ). This reaction strategy could be further extended to synthesize the first bidentate arsanylborane tmeda⋅(BH2AsPh2)2 ( 3 ). Depending on the substituents on the phosphorus, these compounds form different AuI complexes, to build either polymeric tmeda⋅(BH2PH2AuCl)2 ( 4 a ), or monomeric tmeda⋅(BH2PPh2AuCl)2 ( 4 b ) products. These compounds form also neutral oligomeric group 13/15 chain-like molecules by coordination to a boron moiety such as tmeda⋅(BH2PH2BH3)2 ( 5 a ) and tmeda⋅(BH2AsPh2BH3)2 ( 5 b ). DFT calculations provide insight into the differences between the syntheses of mono- and bidentate pnictogenylboranes. 相似文献
29.
Dr. Lan Hu Prof. Dr. Yan Zhao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(32):7702-7710
Outcomes of chemical reactions are generally dominated by the intrinsic reactivities of reaction partners, but enzymes frequently override such constraints to transform less reactive molecules in the presence of more reactive ones. Despite the attractiveness of such catalysis, it is difficult to build synthetic catalysts with these features. Micellar imprinting is a powerful method to create template-complementary binding sites inside protein-sized water-soluble nanoparticles. When a photocleavable functional monomer was used to bind two phosphonate/phosphate templates as transition-state analogues, active sites with predetermined size and shape were formed inside doubly cross-linked micelles through molecular imprinting. Postmodification replaced the binding group with a catalytic pyridyl group, forming highly selective artificial esterases. The catalysts displayed enzyme-like kinetics and turnover numbers that were in the hundreds. The selectivity of the catalysts, derived from the substrate-complementary imprinted active sites, enabled transformation of less reactive esters in the presence of more reactive ones. 相似文献
30.
Xiaomin Ren Miao Guo He Li Chengbin Li Liang Yu Jian Liu Qihua Yang 《Angewandte Chemie (International ed. in English)》2019,58(41):14392-14392